DIENONE PHENOL REARRANGEMENT PDF

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Re2O7 Catalyzed Dienone-Phenol Rearrangement. Zilei Xia,a,b,ǁ Jiadong Hu,a, b,ǁ Zhigao Shen,a,b Qizheng Yao*,a and Weiqing Xie*,b,c a Department of. Dienone–phenol rearrangement of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene -1,4,5(8H)-triones (1) and (2) in acetic anhydride as solvent is the subject of a. The experiment is based on the dienone-phenol rearrangement reaction of the sesquiterpene santonin to give -desmotroposantonin acetate. It challenges.

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Dienone – Wikipedia

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Back to tab navigation Download options Please wait Dienone—phenol rearrangement mechanism of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 H -triones in acetic anhydride solution. Search articles by author Candelaria Goycoolea.

Jump to main content. For reproduction of material from NJC: The results are rationalized in terms of the formation of acylated intermediate cations and schematic representation is provided.

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Authors contributing to RSC publications journal articles, books or book chapters do not need to formally request permission to reproduce material contained in this article dienonee that the correct acknowledgement is given with the reproduced material. In all cases the Ref. Reproduced material should be attributed as follows: Go to our Instructions for using Copyright Clearance Center page for details. The effects of sulphuric and acetic acids are also investigated.

Dienone-phenol rearrangement

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For reproduction of material from all other RSC journals and books: Both substrates show limiting [H 2 SO 4 ] dependence and an inhibiting effect with acetic acid.

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For reproduction of material from PCCP: Previous Article Next Article. Dienone—phenol rearrangement mechanism of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 H -triones in acetic anhydride solution C.

The effect of temperature in the reaction of 1 and that of the C-6 methyl group of 2 are discussed. If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc.

Dienone—phenol rearrangement of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 Rrarrangement -triones 1 and 2 in acetic anhydride as solvent is the subject of a kinetic study. You do not have JavaScript enabled. XX is the XXth reference in the list of references. Fetching data from CrossRef.

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